Jawaharlal Nehru Technological University, Telangana, Electrical & Electronics Engineering Semester 1, Chemistry Syllabus

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Unit - 1 Molecular structure and Theories of Bonding

UNIT 1

Molecular structure and Theories of Bonding

1.1 Atomic and Molecular orbitals

1.2 Linear Combination of Atomic Orbital LCAO

1.3 Molecular orbital of diatomic molecules

1.4 Molecular orbital energy level diagrams of N2 O2 and F2 molecules

1.5 π molecular orbital of butadiene and benzene

1.6 Crystal Field Theory CFT Salient Features of CFT – Crystal Field Splitting of transition metal ion d orbitals in Tetrahedral Octahedral and square planar geometries

1.7 Band structure of solids and effect of doping on conductance

Unit - 2 Water and its treatment

UNIT 2

Water and its treatment

2.1 Introduction – hardness of water – Causes of hardness Types of hardness temporary and permanent – expression and units of hardness – Estimation of hardness of water by complexometric method

2.2 Potable water and its specifications

2.3 Steps involved in treatment of water – Disinfection of water by chlorination and ozonization

2.4 Boiler feed water and its treatment

2.5 Calgon conditioning Phosphate conditioning and Colloidal conditioning

2.6 External treatment of water – Ion exchange process

2.7 Desalination of water – Reverse osmosis

Unit - 3 Electrochemistry and corrosion

UNIT 3

Electrochemistry and corrosion

3.1 Electro chemical cells – electrode potential Standard electrode potential Types of electrodes – calomel Quinhydrone and glass electrode

3.2 Nernst equation Determination of pH of a solution by using quinhydrone and glass electrode

3.3 Electrochemical series and its applications

3.4 Potentiometric titrations

3.5 Batteries – Primary Lithium cell and secondary batteries Lead – acid storage battery and Lithium ion battery

3.6 Causes and effects of corrosion – theories of chemical and electrochemical corrosion – mechanism of electrochemical corrosion

3.7 Types of corrosion Galvanic waterline and pitting corrosion

3.8 Factors affecting rate of corrosion

3.9 Corrosion control methods Cathodic protection – Sacrificial anode and impressed current cathodic methods

3.10 Surface coatings – metallic coatings – methods of application Electroless plating of Nickel.

Unit - 4 Stereochemistry, Reaction Mechanism, and synthesis of drug molecules

Unit 4

Stereochemistry Reaction Mechanism and synthesis of drug molecules

4.1 Introduction to the representation of 3dimensional structures

4.2 Structural and stereoisomers

4.3 Configurations

4.4 Symmetry and chirality

4.5 Enantiomers and Diastereomers

4.6 Optical activity

4.7 Absolute configuration conformation analysis of nbutane

4.8 Substitution reactions Nucleophilic substitution reactions

4.9 Mechanism of SN1 SN2 reactions

4.10 Electrophilic and nucleophilic addition reactions

4.11 Addition of HBr to propene

4.12 Markownikoff and anti Markownikoff’s additions

4.13 Grignard additions on carbonyl compounds

4.14 Elimination reactions Dehydro halogenation of alkyl halides

4.15 Saytzeff rule

4.17 Reduction reactions Reduction of carbonyl compounds using LiAlH4 NaBH4

4.18 Hydroboration of olefins

4.19 Structure synthesis and pharmaceutical applications of Paracetamol and Aspirin.

Unit - 5 Spectroscopic techniques and applications

Unit V

Spectroscopic techniques and applications

5.1 Principles of spectroscopy

5.2 Selection rules and applications of electronic spectroscopy

5.3 Vibrational and rotational spectroscopy

5.4 Basic concepts of Nuclear magnetic resonance Spectroscopy

5.5 Introduction to Magnetic resonance imaging

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Other Subjects of Semester-1
English
Mathematics - i
Basic electrical engineering
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