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Unit - 1 Basic Concepts

Unit 1

Basic concept

1.1 Concept of continuum

1.2 Macroscopic approach

1.3 Closed open and isolated system

1.4 Property state path and process

1.5 Quasistatic process work modes of work.

1.6 Zeroth law of thermodynamics

1.7 Concept of temperature and heat

1.8 Concept of ideal and real gases

Unit - 2 First Law Of Thermodynamics

Unit 2

First Law of Thermodynamics

2.1 Concepts of Internal Energy

2.2 Specific Heat Capacities Enthalpy

2.3 Energy Balance for Closed and Open Systems

2.4 Energy Balance for SteadyFlow Systems.

2.5 SteadyFlow Engineering Devices

2.6 Energy Balance for Unsteady Flow

Unit - 3 Second Law Of Thermodynamics

Unit 3

Second Law of Thermodynamics

3.1 Thermal energy reservoirs

3.2 Heat engines energy conversion

3.3 Kelvin’s and Clausius statements of second law

3.4 Carnot cycle the Carnot Theorem

3.5 Thermodynamic temperature scale

3.6 The Carnot heat engine efficiency

3.7 The Carnot refrigerator and heat pump COP

3.8 Clausius inequality concept of entropy

3.9 Principle of increase of entropy – availability the increase of entropy principle

3.10 Perpetualmotion machines

3.11 Reversible and irreversible processes

3.12 Entropy change of pure substances isentropic processes property diagrams involving entropy entropy change of liquids and solids the entropy change of ideal gases

3.13 Reversible steadyflow work minimizing the compressor work

3.14 Isentropic efficiencies of steadyflow devices and entropy balance.

3.15 Energy a measure of work potential including work potential of energy

3.16 Reversible work and irreversibility

3.17 Secondlaw efficiency

3.18 Exergy change of a system

3.19 Energy transfer by heat work and mass

3.20 The decrease of Exergy principle and exergy destruction

3.21 Energy balance closed systems and control volumes energy balance

Unit - 4 Properties Of Pure Substances

Unit 4

Properties of Pure Substance

4.1 Properties of pure substancesThermodynamic properties of pure substances in solid liquid and vapour phases and Phase rule PV PT TV TS HS diagrams PVT surfaces.

4.2 Thermodynamic properties of steam.

4.3 Calculations of work done and heat transfer in non flow and flow processes

Unit - 5 Power Cycles

Unit 5

Power Cycles

5.1 Vapour and combined power cycles including the Carnot vapor cycle

5.2 Rankine cycle the ideal cycle for vapor power the ideal reheat and regenerative and the secondlaw analysis of vapour power cycles.

5.3 Gas power cycles including basic considerations in the analysis of power cycles

5.4 The Carnot cycle and its value in engineering

5.5 An overview of reciprocating engines air standard assumptions

5.6 Gasoline engine Otto cycle

5.7 Gasturbine Brayton cycle and the secondlaw analysis of gas power cycles

Unit - 6 Ideal And Real Gases And Thermodynamic Relations

Unit 6

Ideal and Real Gases and Thermodynamic Relations

6.1 Gas mixtures – properties ideal and real gases.

6.2 Equation of state Avogadro’s Law Vander Waal’s equation of state Compressibility factor compressibility chart.

6.3 Dalton’s law of partial pressure

6.4 Exact differentials TD relations Maxwell’s relations.

6.5 Clausius Clapeyron equations Joule – Thomson coefficient

Unit - 7 Psychrometry And Psychrometric Charts

Unit 7

Psychrometry and psychometric charts

7.1 Psychrometry and psychometric charts property calculations of air vapour mixtures.

7.2 Psychometric process – Sensible heat exchange processes. Latent heat exchange processes.

7.3 Adiabatic mixing evaporative cooling.

7.4 Use of standard thermodynamic tables

7.5 Mollier diagram

7.6 Psychometric chart and Refrigerant property tables

7.7 Refrigeration cycles including refrigerators and heat pumps

7.8 Heat Pump

7.9 The ideal reversed Carnot vapourcompression refrigeration cycle

7.10 Actual vaporcompression refrigeration cycles heat pump systems

7.11 Gas refrigeration cycles and absorption refrigeration systems.

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