Utkal University, Odisha, Chemistry Semester 6, Inorganic Chemistry-IV Syllabus

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Unit - 1 Organometallic Compounds-I

Unit – 1

Organometallic Compounds – I

1.1 Definition and classification of Organometallic Compounds on the basis of bond types

1.2 Concept of hapticity of organometallic ligands

1.3 Metal carbonyls 18 electron rule

1.4 Electron count of mononuclear Polynuclear and substituted metal carbonyls of 3d series general methods of preparation of mono and binuclear carbonyls of 3d series

1.5 Structures of mononuclear and binuclear of Cr Mn Fe Co and Ni using VBT

1.6 Piacceptor behaviour of CO MO diagram of CO to be discussed 

1.7 Synergic effect and use of IR data to explain extent of back bonding

1.8 Zeises salt Preparation and structure

1.9 Evidences of synergic and comparison of synergic effect with that in carbonyls.

Unit - 2 Organometallic Compounds-II

Unit 2

Organometallic Compounds II

2.1 Metal Alkyls Important structural features of methyl lithium tetramer and trialkyl Aluminium dimer 

2.2 Concept of Multicenter bonding in these compounds

2.3 Role of triethyl aluminium in polymerization of ethane Ziegler –Natta Catalyst

2.4 Species present in ether solution of Grignard reagent and their structures

2.5 Ferrocene Preparation and reactions acetylation Alkyation Metallation Mannich Condensation

2.6 Structure and Aromaticity

2.7 Comparison of Aromaticity and reactivity with that of benzene

Unit - 3 Catalysis By Organometallic Compounds

Unit 3

Catalysis by Organometallic Compounds

3.1 Catalysis by Organometallic Compounds

3.2 Study of Alkene hydrogenation Wilkinsons Catalyst and its mechanism

3.3 Study of Hydroformylation Co salts and its mechanism

3.4 Study of Wacker Process and its mechanism

3.5 Theoretical Principles in Qualitative Analysis H2S Scheme

3.6 Basic principles involved in analysis of cations and anions and solubility products

3.7 Common ion effect

3.7 Principles involved in separation of cations into groups and choice of group reagents

3.8 Interfering anions fluoride and phosphate and need to remove them after Group II

Unit - 4 Thermodynamic & Kinetic Aspects And Reaction Mechanism Of Metal Complexes

Unit 4

Thermodynamic kinetic aspects and reaction mechanism of metal complexes

4.1 Thermodynamic kinetic aspects and reaction mechanism of metal complexes

4.2 Thermodynamic and kinetic stability

4.3 Stepwise and overall formation constants and their relationship

4.4 Factors affecting stability

4.5 Introduction to inorganic reaction mechanismstypes of reaction and classification of substitution reaction

4.6 Substitution reaction of square planar complexes

4.7 Trans effect and its applications

4.8 Theories of transeffect electrostatic polarization and Static piBonding Theory

4.9 Kinetics of octahedral substitution classification of metal ions based on water exchange rate

4.10 General mechanism of ligand substitution reactions in octahedral complexes D I Id Ia

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