Utkal University, Odisha, Chemistry Semester 4, INORGANIC CHEMISTRY-III Syllabus

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Unit - 1 Coordination Chemistry

1.1 Werners theory

1.2 Valence bond theory inner and outer orbital complexes

1.3 Electro neutrality principle and back bonding.

1.4 IUPAC nomenclature of coordination compounds.

1.5 Isomerism in coordination compounds.

1.6 Stereochemistry of complexes with 4 and 6 coordination numbers.

1.7 Labile and inert complexes.

1.8 Crystal field theory.

1.9 Measurement of CFSE weak and strong fields

1.10 Pairing energies.

1.11 Factors affecting the magnitude of 10Dq in octahedral vs. tetrahedral coordination.

1.12 Tetragonal distortions form octahedral geometry.

1.13 JahnTeller theorem.

1.14 Square planar geometry.

1.15 Qualitative aspect of ligand field and MO Theory.

Unit - 2 Transition Elements-I

2.1 Transition Elements 1 General group trends with special reference to electronic configuration colour variable valency

2.2 Magnetic and catalytic properties and ability to form complexes.

2.3 Stability of various oxidation states and e. m. f. Latimer Ebsworth diagrams. Difference between the first second and third transition series.

Unit - 3 Transition Elements-I

3.1 Transition Elements 2 Chemistry of Ti V Cr Mn Fe and Co in various oxidation states excluding their metallurgy

3.2 Lanthanoids and Actinoids Electronic configuration oxidation states colour spectral and magnetic properties

3.3 Lanthanide contraction separation of lanthanides

3.4 General features of actinoids separation of Np Pm Am from U

Unit - 4 Transition Elements-I

4.1 Metal ions present in biological systems.

4.2 Classification of elements according to their action in biological system.

4.3 NaKpump carbonic anhydrase and carboxypeptidase.

4.4 Excess and deficiency of some trace metals. Toxicity of metal ions Hg Pb Cd and As.

4.5 Reasons for toxicity.

4.6 Use of chelating agents in medicine. Iron and its application in biosystems.

4.7 Haemoglobin and myoglobin.

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Other Subjects of Semester-4
Organic chemistry-iii
Physical chemistry-iv
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