Utkal University, Odisha, Chemistry Semester 4, Organic Chemistry-III Syllabus

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Unit - 1 Nitrogen Containing Functional Groups

Unit 1

Nitrogen Containing Functional Groups

1.1 Preparation and important reactions of nitro and compounds nitriles

1.2 Amines Effect of substituent and solvent on basicity

1.3 Preparation and properties

3.1 Preparation of dinitrogen

1.4 Gabriel Phthalimide synthesis.

1.5 Carbylamine reaction.

1.6 Hoffmann s exhaustive methylation.

1.7 Hofmannelimination.

1.8 Distinction between 1degree 2degree and 3degree amines with Hinsberg reagent and nitrous acid

Unit - 2 Diazonium Salts

Unit 2

Diazonium Salts

2.1 Diazonium Salts

2.2 Preparation and their synthetic application.

2.3 Polynuclear Hydrocarbons

2.4 Preparation and structure elucidation and important derivatives of naphthalene and anthracene.

Unit - 3 Heterocyclic Compounds

Unit 3

Heterocyclic Compounds

3.1 Heterocyclic Compounds

3.2 Classification and nomenclature.

3.4 Synthesis reactions and mechanism of substitution reactions of Furan Pyrrole Paal –Knorr synthesis Knorr pyrrole synthesis

3.5 Thiophene Pyridine Hantzsch synthesis Pyrimidine.

3.6 Fischer indole synthesis and Madelung synthesis

3.7 Furfural and furoic acid.

Unit - 4 Alkaloids

Unit 4

Alkaloids

4.1 Alkaloids Natural occurrence General structural features Isolation and their physiological action

4.2 Hoffmanns exhaustive methylation Emdes modification Structure elucidation and synthesis of Hygrine and Nicotine.

4.3 Medicinal importance of Nicotine Hygrine Morphine Cocaine and Reserpine.

4.4 Terpenes.

4.5 Elucidation of structure and synthesis of Citral Neral and aterpineol.

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Other Subjects of Semester-4
Physical chemistry-iv
Inorganic chemistry-iii
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